The NMR 13C and 1H spectra and parameters spectra a luminescence ion europium of Ln(fod)3 and Ln(dpm)3 (where paramagnetic of ions of lantanide Ln3+ = Pr, Sm, Dy, Ho, Er, Eu, Yb, and substrates = 1-, 2-, 3-pic and 3,5-, 2,4,5-, -lut, and [1-4]azafluorene) in CDCl3 and CCl4 were observed at 77 and 300K and lanthanide-induced shift for all of atoms of protons and of carbons, including those of the chelate, were calculated using the complete dipolar-shift equation. If is observed the deviation of symmetry adduct from axial in this case, to is accompanied by increase of the factor are the factors of the coordination: theory - experiment up to RGAM = 0,2 - 0,5; 2). If at an estimation of a hypothesis about structure of a complex the LSR-substrate the basic criteria are carried out some: 1) presence of axial symmetry, 2) stechiometry is 1:1, 3) are authentically divided the dipole and constant superthin interaction are the R-factors of the coordination of theory and of experiment sharply is reduced up to RGAM = 0,001 - 0,015; 3). On sets dipolare lanthanide induced shifts of resonant frequencies of nucleus of a substratum in spectra NMR 13C and 1H is established, that the designed length of coordination communication an ion lanthanide - donor-atoms of a substratum in a solution is in a range dln-Nsubsr = 2,75 - 2,53 Ǻ and on dln-Nsubsr = 0,08 - 0,3 Ǻ more, than for the same adduct LSR-substrate in a crystal.